Nernst Equation Calculator
Calculate reduction potential using the Nernst equation from standard potential, temperature, electrons transferred, and ion activities.
Nernst Equation Calculator
The Nernst Equation Calculator computes the reduction potential of a half-cell or full cell reaction under non-standard conditions. The Nernst equation relates electrode potential to standard potential, temperature, and the activities of oxidized and reduced species.
$$E = E_0 - \frac{RT}{zF} \ln\frac{[\text{red}]}{[\text{ox}]}$$
where $E$ is the reduction potential (V), $E_0$ is the standard reduction potential (V), $R$ is the gas constant (8.314 J/(K·mol)), $T$ is temperature in Kelvin, $z$ is the number of electrons transferred, $F$ is Faraday's constant (96,485 C/mol), and $[\text{red}]/[\text{ox}]$ is the ratio of reduced to oxidized species activities or concentrations.
Example: For a cell with $E_0 = 2.25$ V at 25 °C, $z = 2$, and $[\text{Mg}^{2+}]/[\text{Pb}^{2+}] = 0.020/0.200 = 0.1$, the reduction potential is $E = 2.28$ V.
Related tools: Cell EMF Calculator, Lattice Energy Calculator, and Ionic Strength Calculator.
Frequently Asked Questions
What is the Nernst equation used for?
The Nernst equation calculates how electrode potential changes when concentration, temperature, or pressure deviates from standard conditions. It is essential in electrochemistry for predicting cell voltage.
What is standard reduction potential?
Standard reduction potential ($E_0$) is the electrode potential measured under standard conditions: 25 °C, 1 bar pressure, and unit activity for all species. It is defined relative to the standard hydrogen electrode (0 V).
Can I use concentration instead of activity?
Yes, for dilute solutions activities approximate concentrations. For concentrated or ionic solutions, activity coefficients should be applied for higher accuracy.
What units should temperature be in?
The Nernst equation requires temperature in Kelvin. This calculator accepts Celsius or Kelvin and converts automatically.