Phase Rule Calculator
Calculate degrees of freedom using Gibbs phase rule F = C - P + factor for chemical thermodynamics.
Gibbs Phase Rule Calculator
Gibbs' phase rule relates the number of components, phases, and intensive variables that can change independently in a system at equilibrium.
$$F = C - P + \text{factor}$$
where $F$ is degrees of freedom, $C$ is the number of independent components, $P$ is the number of phases, and factor is 2 when both pressure and temperature can vary, 1 when one is fixed, and 0 when both are fixed.
Example: one component present as solid and vapor ($C=1$, $P=2$) with variable $P$ and $T$ gives $F = 1 - 2 + 2 = 1$. One intensive variable (temperature or pressure) can change while maintaining both phases.
Related: Vapor Pressure Calculator and Partial Pressure Calculator.
Frequently Asked Questions
What is a phase in Gibbs phase rule?
A phase is a region with uniform composition and physical properties, such as solid, liquid, gas, or separate immiscible liquids.
What counts as a component?
A component is the minimum number of chemically independent species needed to describe all phases. It is not simply the number of chemical formulas present.
What are degrees of freedom?
Degrees of freedom are the number of intensive variables (like temperature, pressure, or composition) that can change independently without altering the number of phases.
When is factor equal to zero?
Factor is zero when both pressure and temperature are held constant, such as in some isothermal-isobaric analyses.